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상품코드 : G5D84249020322
Cyclohexene, 99% (사이클로헥센)
재고 소진시, 2~3주 소요됩니다.
판매가 71,390원
부가세 부가세 포함 금액입니다.
구매혜택 적립금 1%
배송방식 일반배송
배송비 주문금액별 차등 (무료)
주문옵션
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    관심상품

     

    A11359 

    Cyclohexene, 99%
    110-83-8
    UN2256
    MFCD00001539
    3
    203-807-8
    II

     

     

    Chemical Properties
    C6H10
    82.15
    -104°
    83-85°
    -20°(-4°F)
    0.811
    1.4460
    Ambient temperatures.
    Colorless liquid
    Immiscible with cold water.
    Literature References

    Protection of the phenolic OH of tyrosine as the cyclohexyl ether has been effected with BF3 etherate. The group can be cleaved with HF or HBr/AcOH: J. Am. Chem. Soc., 100, 3559 (1978).

    Hydrogen donor in catalytic hydrogen-transfer reactions, usually with palladium. For reviews, see: Chem. Rev., 74, 567 (1974); 85, 129 (1985). Examples:

    Hydrogenolysis of benzyloxycarbonyl groups: Synthesis, 685 (1976). Simultaneous cleavage of benzyl and benzyloxycarbonyl groups: J. Chem. Soc., Perkin 1, 490 (1977). Cleavage of benzyl ethers: Synthesis, 396 (1981). With FeCl3, reduction of aryl carbonyl groups to methylene: J. Chem. Soc., Chem. Commun., 757 (1976).

    Conditions have been described for work-up of the ozonide to give the monoacetal of the dialdehyde, the aldehydo-ester, or the dimethyl acetal of the methyl ester: Org. Synth. Coll., 7, 168 (1990).

    Undergoes allylic acetoxylation, catalyzed by Palladium(II)­ acetate, 10516, in the presence of MnO2 and 1,4-benzoquinone: Org. Synth. Coll., 8, 137 (1993).

    Other References:
    906737
    14,2727
    UN2256
    GHS Hazard and Precautionary Statements
    H225-H301-H304
    Highly flammable liquid and vapour.Toxic if swallowed.May be fatal if swallowed and enters airways.
    P210-P241-P301+P310-P303+P361+P353-P405-P501a
    Keep away from heat/sparks/open flames/hot surfaces. - No smoking.Use explosion-proof electrical/ventilating/lighting/ equipment.IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.
    Flammable
    Toxic
    Health Hazard
    위험 및 안전 코드
    11-22-65
    Highly flammable.Harmful if swallowed.Harmful: may cause lung damage if swallowed.
    9-16-23-33-36-60-62
    Keep container in a well-ventilated place.Keep away from sources of ignition - No smoking.Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer).Take precautionary measures against static discharges.Wear suitable protective clothing.This material and its container must be disposed of as hazardous wasteIf swallowed, do not induce vomiting: seek medical advice immediately and show this container or label.
    GW2500000

     



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